Product ID:AMERZINE 15 CORROSION INHIBITOR
MSDS Date:01/21/1998
FSC:6810
NIIN:01-052-1651
Status Code:A
MSDS Number: CKDBS

Emergency Phone: 800-325-3751

Info Phone: 614-790-3333

Preparer: NOT PROVIDED.

Cage: 34897

Telephone: 916-941-3688

Cage: 1KH20

HYDRAZINE (SARA 302/313) (CERCLA)

CAS: 302-01-2

RTECS: MU7175000

OSHA PEL S, 1 PPM

ACGIH TLV: S, 0.01 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:NOT PROVIDED.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: LIVER. EYE: CAN CAUSE
SEVERE IRRITATION, STINGING, TEARING, REDNESS, SWELLING. CAN INJURE
EYE TISSUE. SKIN: CAN CAUSE IRRITATION. SYMPTOMS MAY INCLUDE
REDNESS, BURNING, SKIN DAMAGE. MA Y CAUSE ALLERGIC SKIN REACTION
AND BLISTERING. SWALLOWING: MAY BE HARMFUL OR FATAL. SYMPTOMS MAY
INCLUDE SEVERE STOMACH AND INTESTINAL IRRITATION, NAUSEA, VOMITING,
DIARRHEA. MAY CAUSE BURNS AND DESTR OY TISSUES IN THE MOUTH,
THROAT, AND DIGESTIVE TRACT. LOW BLOOD PRESSURE AND SHOCK MAY OCCUR
AS A RESULT OF SEVERE TISSUE INJURY. INHALATION: MAY BE HARMFUL OR
FATAL. MAY CAUSE SEVERE IRRITATION AND B URNS TO NOSE, THROAT,
RESPIRATORY TRACT.
Explanation of Carcinogenicity:HYDRAZINE HAS BEEN SHOWN TO CAUSE CANCER
IN LABORATORY ANIMALS EXPOSED ORALLY, BY INHALATION, OR BY
INJECTION INTO THE ABDOMEN. IT IS LISTED AS CARCINOGENIC BY IARC
AND NTP.
Effects of Overexposure:SIGNS AND SYMPTOMS OF OVEREXPOSURE TO THIS
MATERIAL THROUGH BREATHING, SWALLOWING, AND/OR PASSAGE OF THE
MATERIAL THROUGH THE SKIN MAY INCLUDE: CENTRAL NERVOUS SYSTEM
DEPRESSION (DIZZINESS, DROWSINESS , WEAKNESS, FATIGUE, NAUSEA,
HEADACHE, UNCONSCIOUSNESS), BLOOD ABNORMALITIES (BREAKAGE OF RED
BLOOD CELLS), KIDNEY DAMAGE, LIVER DAMAGE, CONVULSIONS.
Medical Cond Aggravated by Exposure:PREEXISTING DISORDERS OF THE
FOLLOWING ORGANS (OR ORGAN SYSTEMS) MAY BE AGGRAVATED BY EXPOSURE
TO THIS MATERIAL: SKIN, LUNGS (FOR EXAMPLE, ASTHMA-LIKE
CONDITIONS), LIVER, KIDNEY.

First Aid:EYES: REMOVE FROM EXPOSURE. IMMEDIATELY FLUSH EYES GENTLY
WITH WATER FOR AT LEAST 15 MINUTES WHILE HOLDING EYELIDS APART.
SEEK MEDICAL ATTENTION. SKIN: FLUSH SKIN WITH WATER FOR 15 MINUTES
WHILE REMOV ING CONTAMINATED CLOTHING. SEEK MEDICAL ATTENTION.
SWALLOWING: SEEK MEDICAL ATTENTION. IF INDIVIDUAL IS DROWSY OR
UNCONSCIOUS, DO NOT GIVE ANYTHING BY MOUTH; PLACE ON LEFT SIDE WITH
THE HEAD DOWN. CON TACT PHYSICIAN WHETHER TO INDUCE VOMITING. IF
POSSIBLE, DO NOT LEAVE INDIVIDUAL UNATTENDED. INHALATION: MOVE TO
FRESH AIR. SEEK MEDICAL ATTENTION. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BRE ATHING IS DIFFICULT, ADMINISTER
OXYGEN.

Flash Point:>93.3C, 200.F
Lower Limits:4.7
Upper Limits:99.0
Extinguishing Media:WATER FOG.
Fire Fighting Procedures:WATER MAY BE USED TO KEEP FIE-EXPOSED
CONTAINERS COOL UNTIL FIRE IS OUT. WEAR A SELF-CONTAINED BREATHING
APPARATUS WITH A FULL FACEPIECE OPERATED IN POSITIVE PRESSURE
DEMAND MODE WITH APPROPRIATE TURN -OUT GEAR AND CHEMICAL RESISTANT
PERSONAL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:FLAMMABLE AIR-VAPOR MIXTURE MAY FORM.
HYDRAZINE CAN IGNITE SPONTANEOUSLY WHEN DISPERSED IN AIR AND WHEN
IN CONTACT WITH POROUS MATERIALS SUCH AS EARTH, ASBESTOS, WOOD OR
CLOTH (RAGS SHOULD NEVER BE US ED TO WIPE-UP SPILLS).

Spill Release Procedures:SMALL SPILL: COVER WITH SODA ASH OR SODIUM
BICARBONATE AND MIX. IF EFFERVESCENT, WAIT UNTIL REACTION IS
COMPLETE. SCOOP INTO LARGE BEAKER. LARGE SPILL: ELIMINATE IGNITION
SOURCES. WEAR PROTECTIVE EQUI PMENT. STOP SPILL AT SOURCE. PREVENT
FROM ENTERING SEWERS, DRAINS. IF RUNOFF OCCURS, NOTIFY AUTHORITIES
AS REQUIRED. TRANSFER TO CONTAINERS FOR RECOVERY. ABSORB
UNRECOVERABLE MATERIAL FOR DISPOSAL.
Neutralizing Agent:NOT PROVIDED.

Handling and Storage Precautions:HYDRAZINE-CONTAINING PRODUCTS SHOULD
BE STORED AT TEMPERATURES WELL BELOW THEIR BOILING POINTS, AWAY
FROM IGNITION SOURCES AND OXIDANTS, AND PREFERABLY OUTDOORS. IT
SHOULD BE SHELTERED OUTDOORS AGAINS T DIRECT SUNLIGHT, DIRT, SNOW,
WATER, AND ICE ACCUMULATION. TANK SHOULD BE ELECTRICALLY GROUNDED.
Other Precautions:FOR INDOOR STORAGE AREAS, CONTINUOUS VENTILATION
SHOULD BE PROVIDED. MAJOR STORAGE AREAS SHOULD BE DIKED WITH
CONCRETE TO HOLD AT LEAST 110% OF THE TOTAL STORAGE CAPACITY AND
HAVE A CONCRETE SLAB BELO W THE STORAGE TANK, SO THAT SPILLED
HYDRAZINE WILL NOT BE SOAKED INTO GROUND. CONTAINERS MAY BE HAZA
RDOUS WHEN EMPTIED.

Respiratory Protection:WORKPLACE SHOULD BE MONITORED IF EXPOSURE TO
VAPOR/MISTS EXCEEDS PEL/TLV. ONLY NIOSH APPROVED RESPIRATOR &
CARTRIDGE (TC-23C) IS TO BE USED. MONITOR RESULTS TO ASSESS PROPER
LEVEL OF RESPIRATORY PROTE CTION NECESSARY (FULL FACE PIECE
RESPIRATOR WITH CHEMICAL CARTRIDGES/SELF-CONTAINED BREATHING
APPARATUS). OBSERVE REQUIREMENTS ESTABLISHED IN 29 CFR 1910.134.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL)
EXHAUST VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:POLYVINYL CHLORIDE (PVC).
Eye Protection:CHEMICAL SPLASH GOGGLES IN COMPLIANCE WITH OSHA
REGULATIONS ARE ADVISED.
Other Protective Equipment:TO PREVENT SKIN CONTACT, WEAR IMPERVIOUS
FULL-BODY PROTECTIVE CLOTHING.
Work Hygienic Practices:NOT PROVIDED.
Supplemental Safety and Health
OSHA REGULATIONS ALSO PERMIT OTHER TYPE SAFETY GLASSES. (CONSULT YOUR
INDUSTRIAL HYGIENIST.)

HCC:T4
NRC/State Lic Num:NOT RELEVANT.
Boiling Pt:=100.C, 212.F
B.P. Text:@ 760MMHG
Melt/Freeze Pt:=-13.9C, 7.F
Decomp Temp:Decomp Text:NOT PROVIDED.
Vapor Pres:NO DATA
Vapor Density:>1.00AIR=1
Volatile Org Content %:15
Spec Gravity:1.012 @ 77F
pH:10.5-11.5
Viscosity:NOT PROVIDED.
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER
Solubility in Water:NOT PROVIDED.
Appearance and Odor:PALE YELLOW LIQUID; ODOR NOT DETERMINED
Percent Volatiles by Volume:85.0 - 100
Corrosion Rate:NOT PROVIDED.

Stability Indicator/Materials to Avoid:YES
COPPER, COPPER ALLOYS, LEAD, LEAD ALLOYS, ORGANIC MATERIALS, STRONG
MINERAL ACIDS, STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:EXCESSIVE HEAT
Hazardous Decomposition Products:AMMONIA, CARBON DIOXIDE, CARBON
MONOXIDE, NITROGEN COMPOUNDS.
Conditions to Avoid Polymerization:PRODUCT WILL NOT UNDERGO HAZARDOUS
POLYMERIZATION.

Waste Disposal Methods:MIX WITH EQUAL VOLUME OF SODA ASH AND ADD WATER
TO FORM A SLURRY IN A LARGE CONTAINER. ADD CALCIUM HYPOCHLORITE,
ADD MORE WATER AND LET STAND FOR 2 HRS, NEUTRALIZE AND WASH DOWN
DRAIN WITH EXCESS WATE R IN ACCORDANCE WITH APPLICABLE REGULATIONS.
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STA TE AND
FEDERAL REGULATIONS.

Toxicological Information:NO DATA.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO DATA.

Transport Information:DOT DESCRIPTION: HYDRAZINE, AQUEOUS SOLUTIONS,
6.1, UN3293, III. CONTAINER/MODE: 55 GAL DRUM/TRUCK PACKAGE.

SARA Title III Information:CERCLA REPORTABLE QUANTITY (RQ) : 1 POUND.
SARA 302 COMPONENTS - 40 CFR 355 APPENDIX A: TPQ: 1000 LBS. SECTION
311/312 HAZARD CLASS: IMMEDIATE AND DELAYED. SECTION 313
COMPONENT(S): HYDRAZINE 302-01- 2 15.01%
Federal Regulatory Information:TSCA (TOXIC SUBSTANCES CONTROL ACT)
STATUS: TSCA (UNITED STATES) THE INTENTIONAL INGREDIENTS OF THIS
PRODUCT ARE LISTED. EPA ACCIDENTAL RELEASE PREVENTION 40 CFR 68:
HYDRAZINE TQ: 15000 LBS.
State Regulatory Information:CALIFORNIA PROPOSITION 65: THE FOLLOWING
STATEMENT IS MADE IN ORDER TO COMPLY WITH THE CALIFORNIA SAFE
DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986: THIS PRODUCT
CONTAINS THE FOLLOWING SUBSTANCE(S ) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER. HYDRAZINE. NEW JERSEY RIGHT-TO-KNOW
LABEL INFORMATION: HYDRAZINE 302-01-2. PENNSYLVANIA RIGHT-TO-KNOW
LABEL INFORMATION: HYDRAZINE 302-01-2.